A 3.6 v lithium-based fluorosulphate insertion positive electrode for lithium-ion batteries

Abstract

Li-ion batteries have contributed to the commercial success of portable electronics, and are now in a position to influence higher-volume applications such as plug-in hybrid electric vehicles. Most commercial Li-ion batteries use positive electrodes based on lithium cobalt oxides. Despite showing a lower voltage than cobalt-based systems (3.45 V versus 4 V) and a lower energy density, LiFePO 4 has emerged as a promising contender owing to the cost sensitivity of higher-volume markets. LiFePO 4 also shows intrinsically low ionic and electronic transport, necessitating nanosizing and/or carbon coating. Clearly, there is a need for inexpensive materials with higher energy densities. Although this could in principle be achieved by introducing fluorine and by replacing phosphate groups with more electron-withdrawing sulphate groups, this avenue has remained unexplored. Herein, we synthesize and show promising electrode performance for LiFeSO 4 F. This material shows a slightly higher voltage (3.6 V versus Li) than LiFePO 4 and suppresses the need for nanosizing or carbon coating while sharing the same cost advantage. This work not only provides a positive-electrode contender to rival LiFePO 4, but also suggests that broad classes of fluoro-oxyanion materials could be discovered. © 2010 Macmillan Publishers Limited. All rights reserved.