The rate coefficients for the reaction of OH with methyl vinyl ketone (MVK, CH3C(O)CHCH2) and methacrolein (MACR, CH2C(CH3)CHO) between 232 and 378 K were measured using the pulsed laser photolysis-pulsed laser induced fluorescence (PP-PLIF) technique. The rate coefficient data can be expressed in the Arrhenius form as k1(OH + MVK) = (2.67 ± 0.45) × 10-12 exp((452 ± 130)/ T) and k2(OH + MACR) = (7.73 ± 0.65) × 10-12 exp((379 ± 46)/T) cm3 molecule-1 s-1, where the error limits are 2σ and include estimated systematic errors. The UV absorption cross-sections of MVK and MACR were measured over the wavelength range 250-395 nm using a diode array spectrometer. Absolute quantum yields for loss of MVK and MACR were measured at 308, 337, and 351 nm. The MACR quantum yield, ΦMACR, was <0.01. The MVK quantum yield was both pressure and wavelength dependent and is represented by the expression: Φ0(λ,P)
CITATION STYLE
Gierczak, T., Burkholder, J. B., Talukdar, R. K., Mellouki, A., Barone, S. B., & Ravishankara, A. R. (1997). Atmospheric fate of methyl vinyl ketone and methacrolein. Journal of Photochemistry and Photobiology A: Chemistry, 110(1), 1–10. https://doi.org/10.1016/S1010-6030(97)00159-7
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