Effect of bond-length alternation in molecular wires

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Abstract

Current-voltage (I-V) characteristics for metal-molecule-metal junctions formed from three classes of molecules measured with a simple crossed-wire molecular electronics test-bed are reported. Junction conductance as a function of molecular structure is consistent with I-V characteristics calculated from extended Hückel theory coupled with a Green's function approach, and can be understood on the basis of bond-length alternation. Copyright © 2002 American Chemical Society.

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Kushmerick, J. G., Holt, D. B., Pollack, S. K., Ratner, M. A., Yang, J. C., Schull, T. L., … Shashidhar, R. (2002). Effect of bond-length alternation in molecular wires. Journal of the American Chemical Society, 124(36), 10654–10655. https://doi.org/10.1021/ja027090n

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