In situ infrared spectroscopy at electrochemical interfaces

Abstract

An insight into the in situ FTIR spectroscopy method as applied in Electrochemistry is given. The particular aspects inherent to the electrochemical method are described in a concise form. Selected examples cover the results of about the last 8 years, on a variety of systems including carbon monoxide, small organic molecules and double-layer components (hydrogen, anions and water).The experimental data refer mostly to adsorption on well-defined single-crystal surfaces. Analogies and differences with data from the metal/gas interface are discussed.