A "Turn-on" Fluorescent Sensor for the Selective Detection of Mercuric Ion in Aqueous Media

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Abstract

A water-soluble turn-on fluorescent sensor for Hg(II) is described. Incorporation of soft thioether donors into an aniline-derived ligand framework that can be linked to a fluorescein platform affords sensor MS1, which shows a ∼5-fold increase in integrated emission upon addition of 1 equiv of Hg(II). The synthesis and metal-binding properties of MS1 are discussed, and its ability to detect environmentally relevant concentrations of Hg(II) is demonstrated. Copyright © 2003 American Chemical Society.

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Nolan, E. M., & Lippard, S. J. (2003). A “Turn-on” Fluorescent Sensor for the Selective Detection of Mercuric Ion in Aqueous Media. Journal of the American Chemical Society, 125(47), 14270–14271. https://doi.org/10.1021/ja037995g

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