In the course of the routine use of NMR as an aid for organic chemistry, a day-to-day problem is the identifica- tion of signals deriving from common contaminants (water, solvents, stabilizers, oils) in less-than-analyti- cally-pure samples. This…
Applied Chemistry
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Sensors and sensitivity: A highly luminescent microporous metal-organic framework, Zn(2)(bpdc)(2)(bpee) (bpdc = 4,4'-biphenyldicarboxylate; bpee = 1,2-bipyridylethene), is capable of very fast and reversible detection of the vapors of the…
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Insights into conducting research and the writing of scientific papers are given by Prof. Whitesides in this short essay. The manuscript and its guidelines has been circulated within the Whitesides' research group since 1989.
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By applying the specific fabrication conditions summarized in the Experimental section and post-production annealing at 150 degrees C, polymer solar cells with power-conversion efficiency approaching 5 % are demonstrated. These devices exhibit…
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New, hydrophobic ionic liquids with low melting points (<-30 C to ambient temperature) have been synthesized and investigated, based on 1,3-dialkyl imidazolium cations and hydrophobic anions. Other imidazolium molten salts with hydrophilic anions…
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Organic solar cell research has developed during the past 30 years, but especially in the last decade it has attracted scientific and economic interest triggered by a rapid increase in power conversion efficiencies. This was achieved by the…
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Polymer photovoltaic cells with power conversion efficiencies approaching 5% have been fabricated using titanium oxide (TiOx) as an optical spacer (see Figure). Solar cells with a TiOx layer (deposited via a sol-gel process) between the active layer…
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Here we report enhanced efficiency bulk heterojunction organic solar cells using blend films of regioregular poly(3-hexylthiophene) (P3HT) and 1-(3-methoxycarbonyl)-propyl-1-phenyl-(6,6)C-61 (PCBM) that are subjected to a thermal annealing process.…
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Organic semiconductors have been the subject of active research for over a decade now, with applications emerging in light-emitting displays and printable electronic circuits. One characteristic feature of these materials is the strong trapping of…
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Colloidal nanocrystals are solution-grown, nanometre-sized, inorganic particles that are stabilized by a layer of surfactants attached to their surface. The inorganic cores possess useful properties that are controlled by their composition, size and…
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Low-cost photovoltaic energy conversion using conjugated molecular materials has become increasingly feasible through the development of organic 'bulk heterojunction (BHJ)' structures(1-7), where efficient light-induced charge separation is enabled…
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THE large-scale use of photovoltaic devices for electricity generation is prohibitively expensive at present: generation from existing commercial devices costs about ten times more than conventional methods 1. Here we describe a photovoltaic cell,…
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Use of amphiphilic triblock copolymers to direct the organization of polymerizing silica species has resulted in the preparation of well-ordered hexagonal mesoporous silica structures (SBA-15) with uniform pore sizes up to approximately 300…
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Graphene sheets-one-atom-thick two-dimensional layers of sp2-bonded carbon-are predicted to have a range of unusual properties. Their thermal conductivity and mechanical stiffness may rival the remarkable in-plane values for graphite (approximately…
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Graphene is the name given to a two-dimensional sheet of sp2-hybridized carbon. Its extended honeycomb network is the basic building block of other important allotropes; it can be stacked to form 3D graphite, rolled to form 1D nanotubes, and wrapped…
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Organic thin-film transistors (OTFTs) have lived to see great improvements in recent years. This review presents new insight into conduction mechanisms and performance characteristics, as well as opportunities for modeling properties of OTFTs. The…
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The synthesis, characterization, and proposed mechanism of formation of a new family of silicate/aluminosilicate mesoporous molecular sieves designated as M41S is described. MCM-41, one member of this family, exhibits a hexagonal arrangement of…
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The integration of novel materials such as single-walled carbon nanotubes and nanowires into devices has been challenging, but developments in transfer printing and solution-based methods now allow these materials to be incorporated into large-area…
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A review with 409 refs. Mechanism and components (monomers, initiators, catalysts, ligands, solvents, and additives) for atom transfer radical polymn. (ATRP) are introduced. Polymers made by ATRP methods are discussed. They are gradient copolymer,…
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An improved method for the preparation of graphene oxide (GO) is described. Currently, Hummers' method (KMnO(4), NaNO(3), H(2)SO(4)) is the most common method used for preparing graphene oxide. We have found that excluding the NaNO(3), increasing…
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Ph.D. StudentMeerholz Group, Departent of Chemistry, University of Cologne -
Student (Master)Technical University of Denmark -
Assistant ProfessorBrooklyn, New York, United States -
Post DocUniversité des Sciences et Technologies de Lille -
Ph.D. StudentKagami Memorial Research Institute for Materials Science and Technology, Waseda University.
