A brief history and review of geopolymer technology is presented with the aim of introducing the technology and the vast categories of materials that may be synthesized by alkali-activation of aluminosilicates. The fundamental chemical and…
Cement
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5,650 papers
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Geopolymers are generally believed to provide good fire resistance due to their ceramic-like properties. Previous experimental studies on geopolymer under elevated temperatures have mainly focused on metakaolin-based geopolymers. This paper presents…
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This paper assesses the mechanical and durability performance of concretes produced using alkali silicate-activated ground granulated blast furnace slag as sole binder. Alkali-activated concretes are formulated with 300, 400 and 500 kg slag per m3…
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The increase in strength and evolution of crystalline phases in inorganic polymer cement, made by the alkali activation of slag, Class C and Class F fly ashes, was followed using compressive strength test and synchrotron X-ray diffraction. In order…
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Some of the physical, chemical and mineralogical characteristics of Portland cement and related materials relevant to nuclear waste immobilization are defined. The ability to condition and maintain a high aqueous pH is undoubtedly the most important…
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The effects of geopolymer binder systems exposed to elevated temperatures are examined. Geopolymers investigated were synthesized from metakaolin, activated by combinations of sodium/potassium silicate and sodium/potassium hydroxide. The specimens…
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The reaction kinetics and mechanism of geopolymers are studied. The dissolved silicate concentration decreases from the beginning of the reaction. A characteristic time 't(0,vit)' for the setting of the reaction mixture is derived from isothermal…
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Osteoinduction is the process by which osteogenesis is induced. It is a phenomenon regularly seen in any type of bone healing process. Osteoinduction implies the recruitment of immature cells and the stimulation of these cells to develop into…
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The microscopic study of a set of alkali-activated and thermally cured fly ash samples enabled the authors to establish a descriptive model for the microstructural development of fly ash-based cementitious geopolymers. The morphology of most fly ash…
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The development of the pore structure of geopolymers synthesized from class F fly ash was studied using electron microscopy and porosimetry. Fly-ash-based geopolymer can be classified as a mesoporous aluminosilicate material, with a Si/Al compn.…
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This study investigated mechanical and permeability properties at early ages of an alkali-activated slag concrete (AASC) reinforced with steel fibers. The compressive, splitting tensile and flexural strengths, flexural notch sensitivity, pull-out…
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The various (vitreous and crystalline) components of two type F fly ashes are quantified in this paper using three techniques: chemical analysis with selective solutions, X-ray powder diffraction combined with the Rietveld method and nuclear…
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This study has investigated the corrosion of different hardened cementing materials, such as Portland cement (PC), alkali-activated blast furnace slag cement (ASC), lime-fly ash (LFA) blend and high alumina cement with gypsum and lime (HAC), in pH 3…
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This article reports the thermal characteristics of geopolymers prepared with a class F fly ash containing 15 wt% iron oxide and 20 wt% alpha-quartz. The characterization techniques used included dilatometry, TGA, DTA, XRD, and SEM. Geopolymer…
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The disintegration of concrete structures made of ordinary Portland cement (OPC) is a worrying topic of increasing significance. The development of new binders with longer durability is therefore needed. Alkali-activated binders have emerged as an…
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