C60-induced alkyne-alkyne coupling and alkyne scission reactions of a tungsten tris(diphenylacetylene) complex.
Chemical Communications (2011)
- PubMed: 21103456
Available from www.ncbi.nlm.nih.gov
or
Abstract
Reaction of W(NCMe)(η(2)-PhCCPh)(3) with C(60) affords W(η(3)-NC(Me)C(60))(η(4),η(2)-C(6)Ph(6)) (2) and W(CPh)(NCMe)(η(2)-C(60)) (η(3),η(2)-C(5)Ph(5)) (3). The hexaphenylbenzene species of 2 shows an η(4)-butadiene + η(2)-olefin bonding mode and the nitrile carbon is inserted into one 6:5-ring junction of C(60). Compound 3 contains an η(3),η(2)-pentaphenylcyclopentadienyl and a benzylidyne group from 2 + 2 + 1 cyclization and scission reactions of the diphenylacetylene ligands.
Sign up today - FREE
Mendeley saves you time finding and organizing research. Learn more
- All your research in one place
- Add and import papers easily
- Access it anywhere, anytime
Start using Mendeley in seconds!
Readership Statistics
2 Readers on Mendeley
by Discipline
50% Chemistry
by Academic Status
50% Doctoral Student
50% Student (Postgraduate)
by Country
50% Japan
50% Germany