Chiral dirhodium(II) carboxylates: New insights into the effect of ligand stereo-purity on catalyst structure and enantioselectivity

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Abstract

The current report contributes to the understanding of the stereoselectivity of chiral dirhodium(II) carboxylate catalysts carrying N-protected tert-leucine ligands. Investigating the possible effect of ligand stereo-purity on catalyst structure and enantioselectivity was carried out. This was justified through a new X-ray crystal structure for Rh2(S,S,S,R-PTTL)4 diastereomer.

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Adly, F. G., Bollard, H., Gardiner, M. G., & Ghanem, A. (2018). Chiral dirhodium(II) carboxylates: New insights into the effect of ligand stereo-purity on catalyst structure and enantioselectivity. Catalysts, 8(7). https://doi.org/10.3390/catal8070268

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