Calculations of crystal distortions in Cu1-xNi xCr2O4 and Fe1-xNi xCr2O4 based on effective Hamiltonians in which the orbital states of the Jahn-Teller ions interact with bulk strains are presented. The derivation of the effective Hamiltonian from a microscopic Hamiltonian is discussed in some detail in the case of Cu1-xNi xCr2O4. It is discussed that a local distortion accompanying each orbital state quenches the spin-orbit coupling whose role in determining the phase diagram was emphasized previously. The present calculations which neglect the spin-orbit coupling can reproduce almost quantitatively the observed phase diagrams of the mixed crystals. It is pointed out that the jump of | c/a-1 | at the cubic-to-tetragonal transition decreases when x approaches a critical concentration xc from both sides, which is supported by experiment. © 1968 The American Institute of Physics.
CITATION STYLE
Kanamori, J., Kataoka, M., & Itoh, Y. (1968). Cooperative Jahn-Teller distortion in mixed chromites. Journal of Applied Physics, 39(2), 688–689. https://doi.org/10.1063/1.2163581
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