Electrodiffusion of alkali ions in alkali niobophosphate glasses and glass-forming melts

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Abstract

Electrical conductivity of Li(Na,K)2O-Nb2O5-P2O5 glasses and glass-forming melts has been measured in a wide temperature range (298-1173 K). Logarithm of the preexponential factor and activation energy of migration have been determined. Mixed alkali effect has been observed in niobophosphate glass-forming melts. Diffusion coefficients for Li+, Na+, and K+ ions have been calculated. The influence of the type of alkali ion and Nb2O5 content on the diffusion coefficients has been determined.

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Markov, V. A., Sokolov, I. A., Kurushkin, M. V., & Povolotskiy, A. V. (2019). Electrodiffusion of alkali ions in alkali niobophosphate glasses and glass-forming melts. International Journal of Applied Glass Science, 10(1), 69–74. https://doi.org/10.1111/ijag.12435

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