The iridium-catalyzed borylation of pyrene, using 4,4′-dimethyl-2,2′-bipyridine as the ligand, in the presence of t-BuOK, gave a mixture of 2,4,7,9-tetrakis(Bpin)-pyrene (c4) and its 2,4,7,10-isomer (m4) in a 2.2:1 ratio, and the selectivity of the Ir-catalyzed borylation of pyrene is kinetically determined and can be influenced to some extent by the nature of the ligand.
CITATION STYLE
Ji, L., Fucke, K., Bose, S. K., & Marder, T. B. (2015). Iridium-catalyzed borylation of pyrene: Irreversibility and the influence of ligand on selectivity. Journal of Organic Chemistry, 80(1), 661–665. https://doi.org/10.1021/jo5024014
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