This work demonstrates for the first time the phenomenon of continuous percrystallization using a carbon membrane derived from the pyrolysis of food grade sugar. In addition, it is also the first demonstration of membranes separating solute from solvent and delivering dry crystals in a single step. This is contrary to membrane crystallization, which requires two further processing steps to filter crystals from a solution followed by drying the wet crystal particles. The results indicate that carbonised sugar membranes can confer ideal conditions of super-saturation, leading to instantaneous and continuous percrystallization of compounds at the permeate side of the membrane. As a result, very high percrystallization production rates of up to 55,000 kg m−2 per year are achieved. It is proposed that the percrystallization occurs in a wet thin-film modulated by solution permeation via the mesopores of the membrane, where vapour and crystals are separated at the membrane's solid-liquid-vapour interface. The potential deployment of this novel technology is further demonstrated for a wide range of crystallization applications in chemical, hydrometallurgy, food and pharmaceutical industries.
CITATION STYLE
Motuzas, J., Yacou, C., Madsen, R. S. K., Fu, W., Wang, D. K., Julbe, A., … Diniz da Costa, J. C. (2018). Novel inorganic membrane for the percrystallization of mineral, food and pharmaceutical compounds. Journal of Membrane Science, 550, 407–415. https://doi.org/10.1016/j.memsci.2017.12.077
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