Proton tunneling in a hydrogen bond measured by cross-relaxation field-cycling NMR

Abstract

A field-cycling NMR pulse sequence is described for studying cross-relaxation between unlike nuclear spins in the solid state. The technique has been applied to study proton tunneling in the hydrogen bonds of a carboxylic acid containing 19F and 1H spins. By studying the B-field dependence of the off-diagonal element of the relaxation matrix that characterizes the longitudinal polarizations, an accurate measure of the proton transfer rate is obtained. © 2005 Elsevier Inc. All rights reserved.