Silver Makes Better Electrical Contacts to Thiol-Terminated Silanes than Gold

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Abstract

We report that the single-molecule junction conductance of thiol-terminated silanes with Ag electrodes are higher than the conductance of those formed with Au electrodes. These results are in contrast to the trends in the metal work function Φ(Ag)

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Li, H., Su, T. A., Camarasa-Gómez, M., Hernangómez-Pérez, D., Henn, S. E., Pokorný, V., … Venkataraman, L. (2017). Silver Makes Better Electrical Contacts to Thiol-Terminated Silanes than Gold. Angewandte Chemie - International Edition, 56(45), 14145–14148. https://doi.org/10.1002/anie.201708524

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