Bimetallic complex compounds of bis(.eta.-cyclopentadienyl)tungsten dihydride

  • Aripovskii A
  • Bulychev B
  • Krivdin L
  • et al.
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Abstract

Cp2WH2.AlX3 (X = Cl, Br, iodo; Cp = .eta.5-cyclopentadienyl), Cp2WH2.MXn (M = Zn, Cu, Fe, Co), [(Cp2WH2)2Cu]Cl2, Cp2WH2.MX2.L (M = Zn, Fe; L = THF, DMF) were obtained by reaction of Cp2WH2 with dry metal halides. The nature of the coordination of hydride bonds was confirmed by IR and NMR spectra.

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Aripovskii, A. V., Bulychev, B. M., Krivdin, L. B., & Polyakova, V. B. (1981). Bimetallic complex compounds of bis(.eta.-cyclopentadienyl)tungsten dihydride. Zhurnal Neorganicheskoi Khimii, 26(8), 2109–2111.

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