Concurrently pumped ultrasonic spray coating for donor:acceptor and thickness optimization of organic solar cells

Abstract

We assess the utility of concurrent spray coating to efficiently screen and optimize solutions for organic solar cells. With this technique two independent solutions are coaxially pumped to the ultrasonic nozzle tip of the spray coater, where a micron-scale mist of droplets, each consisting of one of the two respective solutions with negligible mixing, is ejected toward the substrate. Concurrent spray coating is shown to allow the scanning of two important photoactive layer parameters: thickness, by concurrently diluting concentrated donor:acceptor (D:A) solution with pure solvent, and D:A ratio by concurrently spraying independent solutions of donor and acceptor. The assessment is done using the archetypal poly(3-hexylthiophene) (P3HT):(6,6)-phenyl C61-butyric acid methyl ester (PCBM) system. By allowing the droplets to coalesce on the substrate prior to drying, the resulting film realizes a favorable morphology, confirmed via high-performance OSC devices, with a peak efficiency of 4.1%, 72% fill factor, 9.3 mA/cm2 short circuit current density, and a 620 mV open circuit voltage. © 2012 Elsevier B.V. All rights reserved.