The homoleptic zinc(ii) and ruthenium(ii) metal complexes of bis(tridentate) 9-acridine and 10-methyl-9-acridinium-substituted terpyridines were tested for their suitability as triplet photosensitizers (PS) using the photooxidation of 1,5-dihydroxynaphthalene (DHN) to Juglone as a model reaction. Singlet oxygen (O21Δg) generation is superior or comparable to Ru(bpy)32+ for the acridine complexes, whereas the acridinium complexes are ineffective. The molecular structure of the bis(9-(5-([2,2′:6′,2′′-terpyridin]- 4′-yl)thien-2-yl)-10-methylacridinium)zinc(ii) complex ([Zn(MeATT) 2][PF6]4) is determined by X-ray structure analysis, whereas for other complexes DFT calculations were performed for structural parameters to obtain insights into their electronic properties. © The Royal Society of Chemistry and Owner Societies.
CITATION STYLE
Eberhard, J., Peuntinger, K., Rath, S., Neumann, B., Stammler, H. G., Guldi, D. M., & Mattay, J. (2014). A study of acridine and acridinium-substituted bis(terpyridine)zinc(ii) and ruthenium(ii) complexes as photosensitizers for O2 ( 1Δg) generation. Photochemical and Photobiological Sciences, 13(2), 380–396. https://doi.org/10.1039/c3pp50349f
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