Water adsorption characteristics of MIL-101 for heat-transformation applications of MOFs

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Abstract

The adsorption of water vapor in the highly porous metal-organic framework (MOF) of 3D-[Cr3F(H2O)2O(bdc)3 ·∼25H2O] (MIL-101) (bdc = benzene-1,4-dicarboxylate, terephthalate) of up to 1 g of water per gram of sorbent material (between 140 °C and 40 °C under a water vapor pressure of 5.6 kPa) together with the stability over several cycles makes MIL-101 the most promising material, so far, for heat transformation applications like thermally driven heat pumps or adsorption chillers. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Ehrenmann, J., Henninger, S. K., & Janiak, C. (2011). Water adsorption characteristics of MIL-101 for heat-transformation applications of MOFs. European Journal of Inorganic Chemistry, (4), 471–474. https://doi.org/10.1002/ejic.201001156

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