Nanoporous gold as an active low temperature catalyst toward CO oxidation in hydrogen-rich stream

Abstract

Preferential CO oxidation (PROX) was investigated by using dealloyed nanoporous gold (NPG) catalyst under ambient conditions. Systematic investigations were carried out to characterize its catalytic performance by varying reaction parameters such as temperature and co-existence of CO 2 and H 2 O, which revealed that NPG was a highly active and selective catalyst for PROX, especially at low temperature. At 20 C, the exit CO concentration could be reduced to less than 2â€...ppm with a turnover frequency of 4.1 × 10 -2 â€...s -1 at a space velocity of 120,000â€.. .mL h -1 g -1 cat. and its high activity could retain for more than 24 hours. The presence of residual Ag species in the structure did not seem to improve the intrinsic activity of NPG for PROX; however, they contributed to the stabilization of the NPG structure and apparent catalytic activity. These results indicated that NPG might be readily applicable for hydrogen purification in fuel cell applications.