Multicolor Luminescent Carbon Dots: Tunable Photoluminescence, Excellent Stability, and Their Application in Light-Emitting Diodes

Abstract

Carbon dots (CDs) are attracting much interest due to their excellent photoelectric properties and wide range of potential applications. However, it is still a challenge to regulate their bandgap emissions to achieve full-color CDs with high emissions. Herein, we propose an approach for producing full-color emissive CDs by employing a solvent engineering strategy. By only tuning the volume ratio of water and dimethylformamide (H2O/DMF), the photoluminescence (PL) emission wavelengths of the CDs can be changed from 451 to 654 nm. Different fluorescence features of multicolor CDs were systematically investigated. XRD, SEM, TEM, Abs/PL/PLE, XPS, and PL decay lifetime characterizations provided conclusive evidence supporting the extent to which the solvent controlled the dehydration and carbonization processes of the precursors, leading to a variation in their emission color from red to blue. The as-prepared CDs exhibited excellent and stable fluorescence performance even after being heated at 80 °C for 48 h and with UV light continuously irradiated for 15 h. Based on their excellent fluorescent properties and photothermal stability, bright multicolor light-emitting diodes with a high CRI of up to 91 were obtained. We anticipate that these full-color emissive CDs are beneficial for applications in lighting, display, and other fields.