Abstract
The effective binding of oligosaccharides with large association constants (K=105 - 106M-2) is achieved with the novel scaffold 1. The binding takes place in aqueous media according to a positive homotropic allosterism to form 1:2 1:saccharide complexes.
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Sugasaki, A., Ikeda, M., Takeuchi, M., & Shinkai, S. (2000). Novel oligosaccharide binding to the cerium(IV) bis(porphyrinate) double decker: Effective amplification of a binding signal through positive homotropic allosterism. Angewandte Chemie - International Edition, 39(21), 3839–3842. https://doi.org/10.1002/1521-3773(20001103)39:21<3839::AID-ANIE3839>3.0.CO;2-2
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