Ta2 o5 nanocrystals strengthened mechanical, magnetic, and radiation shielding properties of heavy metal oxide glass

Abstract

In this study, for the first time, diamagnetic 5d0 Ta5+ ions and Ta2 O5 nanocrystals were utilized to enhance the structural, mechanical, magnetic, and radiation shielding of heavy metal oxide glasses. Transparent Ta2 O5 nanocrystal-doped heavy metal oxide glasses were obtained, and the embedded Ta2 O5 nanocrystals had sizes ranging from 20 to 30 nm. The structural analysis of the Ta2 O5 nanocrystal displays the transformation from hexagonal to orthorhombic Ta2 O5. Structures of doped glasses were studied through X-ray diffraction and infrared and Raman spectra, which reveal that Ta2 O5 exists in highly doped glass as TaO6 octahedral units, acting as a network modifier. Ta5+ ions strengthened the network connectivity of 1–5% Ta2 O5-doped glasses, but Ta5+ acted as a network modifier in a 10% doped sample and changed the frame coordination units of the glass. All Ta2 O5-doped glasses exhibited improved Vicker’s hardness, magnetization (9.53 × 10−6 emu/mol), and radiation shielding behaviors (RPE% = 96–98.8%, MAC = 32.012 cm2 /g, MFP = 5.02 cm, HVL = 0.0035–3.322 cm, and Zeff = 30.5) due to the increase in density and polarizability of the Ta2 O5 nanocrystals.