Pyrolysis Kinetics of 1-Propyronitrile Imidazolium Trifluoroacetate Ionic Liquid Using Thermogravimetric Analysis

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Abstract

In this research work pyrolysis characteristics of 1-propyronitrile imidazolium trifluoroacetate was studied using non-isothermal thermogravimetric analysis (TGA). Pyrolysis experiments were conducted in inert condition at three heating rates; 10, 20, and 30°C/min. The value of activation energy (Ea) and pre-exponential factor (A) were calculated by Kissinger-Akahira-Sunose (KAS) methods were 173.18 KJ/mol and 5.40×1016 s -1, while, the Ea and A calculated from Flyyn-Wall-Ozawa (FWO) and Starink methods were 172.48 KJ/mol and 173.44 KJ/mol, and 4.53×1016 s-1 and5.77×1016 s-1, respectively. The results presented that the values of kinetics parameters calculated by these three methods are in close agreement with each other.

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Khan, A. S., Man, Z., Bustam, M. A., Kait, C. F., Ullah, Z., Sarwono, A., & Wilfred, C. D. (2016). Pyrolysis Kinetics of 1-Propyronitrile Imidazolium Trifluoroacetate Ionic Liquid Using Thermogravimetric Analysis. In Procedia Engineering (Vol. 148, pp. 1332–1339). Elsevier Ltd. https://doi.org/10.1016/j.proeng.2016.06.575

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