A new protocol for CO gas-free carbonylation, in which aldehydes are used as a substitute for CO, is described. The protocol consists of two Rh-mediated processes; the Rh-mediated decarbonylation of aldehydes, which leads to the formation of Rh carbonyl, and subsequent Rh-catalyzed carbonylative cyclization utilizing the in situ formed Rh carbonyl species. © 2008 IUPAC.
CITATION STYLE
Morimoto, T., Fujioka, M., Fuji, K., Tsutsumi, K., & Kakiuchi, K. (2008). Rhodium-catalyzed CO gas-free carbonylative cyclization using aldehydes. In Pure and Applied Chemistry (Vol. 80, pp. 1079–1087). https://doi.org/10.1351/pac200880051079
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