Diglycolamic acid anchored on polyamine matrix for the mutual separation of Eu(III) and Am(III)

Abstract

Diglycolamic acid was anchored on a polyamine matrix and the product (PA-DGAH) was characterized by ion-exchange capacity measurement, TG-DTA and FT-IR spectroscopy. The extraction behavior of Am(III) and Eu(III) in PA-DGAH was studied from dilute nitric acid medium to examine the feasibility using the anchored adsorbent for their mutual separation. The effect of various parameters such as the duration of equilibration, concentration of europium, nitric acid and diethylenetriaminepentaacetic acid (DTPA) in aqueous phase on the distribution coefficient (Kd) of Am(III) and Eu(III) was studied. The distribution coefficient decreased with increase in the concentration of nitric acid. Rapid extraction of metal ions in the initial stages of equilibration followed by the establishment of equilibrium occurred within 4 h. The data on the rate of uptake of Am(III) and Eu(III) were fitted into pseudo-first order and pseudo-second order rate equation. The extraction isotherm was fitted to Langmuir and Freundlich adsorption models and the apparent europium extraction capacity was determined. The mechanism of extraction was elucidated and the conditions needed for efficient separation of Am(III) from Eu(III) was optimized using DTPA. The study indicated the possibility of using PA-DGAH for the separation of Eu(III) from Am(III) with high separation factors.