Fabrication of PAN electrospun nanofibers modified by tannin for effective removal of trace Cr(III) in organic complex from wastewater

Abstract

Removal of chromium ions is significant due to their toxicity and harmfulness, however it is very difficult to remove trace Cr(III) complexed with organics because of their strong stability. Herein, a novel electrospun polyacrylonitrile (PAN) nanofibers (NF) adsorbent was fabricated and modified by tannic acid (TA) by a facile blend electrospinning approach for removal of trace Cr(III) in an organic complex. Utilizing the large specific area of nanofibers in the membrane and the good affinity of tannic acid on the nanofibers for hydrolyzed collagen by hydrophobic and hydrogen bonds, the as-prepared PAN-TA NFM exhibited good adsorption toward Cr(III)-collagen complexes and effective reduction of total organic carbon in tannage wastewater. The maximal adsorption capacity of Cr(III) is 79.48 mg g-1 which was obtained at the pH of 7.0 and initial Cr(III) concentration of 50 mg g-1. Importantly, the batch adsorption could decrease the Cr(III) concentration from 10-20 mg L-1 to under 1.5 mg L-1, which showed great application potential for the disposal of trace metal ions in organic complexes from wastewater.