Tuning diffusion paths in shaped ceria nanocrystals

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Abstract

Mass diffusion controls material structuring from the atomic to the macro-scale defining properties and functionalities. We show here that surface energy in Ce0.9Gd0.1O3-d shaped nanocrystals, i.e. nanocubes, nanorods and spherical nanoparticles, can control solid state diffusion mechanisms over a long range, leading to extreme microstructural diversity.

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Esposito, V., Kabir, A., Rosa, M., Van Nong, N., Rodrigues, T. S., Rodrigues, L. N., … Fonseca, F. C. (2019). Tuning diffusion paths in shaped ceria nanocrystals. CrystEngComm, 21(27), 4025–4029. https://doi.org/10.1039/c9ce00414a

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