Methyl 4,5-diacetoxy-1-oxo-2-phenylperhydro-4,6-epoxycyclopenta-[c] pyridine-7-carboxylate ethanol solvate

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Abstract

The title compound, the product of an acid-catalysed Wagner-Meerwein skeletal rearrangement, crystallizes as an ethanol monosolvate, C 20H21NO8·C2H6O. The title mol-ecule comprises a fused tricyclic system containing two five-membered rings (cyclo-pentane and tetra-hydro-furan) in the usual envelope conformations and one six-membered ring (piperidinone) adopting a flattened twist-boat conformation.

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Gurbanov, A. V., Nikitina, E. V., Airiyan, I. K., Zaytsev, V. P., & Khrustalev, V. N. (2009). Methyl 4,5-diacetoxy-1-oxo-2-phenylperhydro-4,6-epoxycyclopenta-[c] pyridine-7-carboxylate ethanol solvate. Acta Crystallographica Section E: Structure Reports Online, 65(12). https://doi.org/10.1107/S1600536809045528

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