Preparation and Characterization of Cellulose Composite Hydrogels From Tea Residue and Single-Walled Carbon Nanotube Oxides and Its Potential Applications

Abstract

Hydrogels were prepared from tea cellulose with the addition of single-walled carbon nanotube oxides in 1-allyl-3-methylimidazolium chloride. Single-walled carbon nanotube oxides/tea cellulose hydrogels (TCH-SWNTs) were characterized by Fourier transform infrared, x-ray diffraction, texture profile analysis, and thermogravimetric analysis. The adsorption capacity of methylene blue using the prepared hydrogels was also investigated. The hydrogels exhibited greater thermal stability and intensive textural property with the addition of single-walled carbon nanotube oxides. Compared with undoped TCHs, the weight loss peak moved from 280 to 323°C, and the values of hardness, fracturability, gumminess, and resilience were 8.4, 5.3, 10.8, and 1.9, respectively, times higher than that of TCHs. As an absorbent of methylene blue, TCH-SWNTs accorded to a pseudo-second-order kinetic model, good adsorption capacity (13.8 mg/g), and good adsorption ratio (27.59%) and showed potential as a drug carrier.