Ionic conductivity in the metal-organic framework UiO-66 by dehydration and insertion of lithium tert-butoxide

142Citations
Citations of this article
169Readers
Mendeley users who have this article in their library.
Get full text

Abstract

Shields up! Post-synthetic modification of the secondary building units in the metal-organic framework UiO-66 (Zr6O4(OH) 4(O2CR)12) by dehydration and subsequent grafting of LiOtBu (see picture, green) yields a solid Li+ electrolyte with a conductivity of 1.8×10-5S cm-1 at 293K. As the grafting leads to screening of the anionic charge, the activation energy for ionic conduction is significantly lower than when Li+ is introduced through deprotonation. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Cite

CITATION STYLE

APA

Ameloot, R., Aubrey, M., Wiers, B. M., Gõmora-Figueroa, A. P., Patel, S. N., Balsara, N. P., & Long, J. R. (2013). Ionic conductivity in the metal-organic framework UiO-66 by dehydration and insertion of lithium tert-butoxide. Chemistry - A European Journal, 19(18), 5533–5536. https://doi.org/10.1002/chem.201300326

Register to see more suggestions

Mendeley helps you to discover research relevant for your work.

Already have an account?

Save time finding and organizing research with Mendeley

Sign up for free