Four two-dimensional lanthanide(III)-4,4-biphenyldicarboxylate complexes: Syntheses, structures, magnetic and luminescent properties

3Citations
Citations of this article
11Readers
Mendeley users who have this article in their library.

Abstract

Four novel Ln-bpdc coordination polymers [Ln(bpdc)(NO3)(DMA)2] [Ln = La(1), Pr(2), Sm(3), Eu(4)] [Ln = lanthanide, H2bpdc = 4,4-biphenyldicarboxylate acid and DMA = dimethylacetamide] have been solvothermally synthesized and structurally characterized by elemental analyses, IR spectra and single-crystal X-ray diffraction. 1-4 crystallize in the monoclinic space group P21/c and show a 2-D layer constructed from 1-D Ln-organic chain and tetradentate bpdc2 - ligand. The magnetic behavior of 2-4 has been investigated. The solid-state photoluminescent measurement illustrates that Eu(4) displays the strong fluorescent emissions, which demonstrate that π-rich aromatic organic bpdc2 - ligands can efficiently transfer energy to the EuIII ions. In addition, thermogravimetric analysis of Pr(2) is also described.

Cite

CITATION STYLE

APA

Lu, Y. B., Jin, S., Zhu, S. D., Zhang, S. Y., Lou, G. T., & Xie, Y. R. (2014). Four two-dimensional lanthanide(III)-4,4-biphenyldicarboxylate complexes: Syntheses, structures, magnetic and luminescent properties. Inorganic Chemistry Communications, 49, 120–123. https://doi.org/10.1016/j.inoche.2014.09.031

Register to see more suggestions

Mendeley helps you to discover research relevant for your work.

Already have an account?

Save time finding and organizing research with Mendeley

Sign up for free