Skip to main content

Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent

19Citations
Citations of this article
15Readers
Mendeley users who have this article in their library.
Get full text
This PDF is freely available from an open access repository. It may not have been peer-reviewed.

Abstract

A dinuclear double end-on azido bridged Ni(II) complex [Ni2L2(μ-1,1-N3)2(N3)2] (1) with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) has been synthesized and characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, magnetic measurements and DFT studies. In complex 1 intra-dimer ferromagnetic coupling between Ni2+ ions (J = +12.0(2) cm−1) and inter-dimer antiferromagnetic interaction (δ = −0.8(3) cm−1) were observed. DFT-BS calculations provided explanation of ferromagnetic exchange coupling in complex 1.

Cite

CITATION STYLE

APA

Romanović, M., Čobeljić, B. R., Pevec, A., Turel, I., Spasojević, V., Tsaturyan, A. A., … Milenković, M. R. (2017). Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girard’s T reagent. Polyhedron, 128, 30–37. https://doi.org/10.1016/j.poly.2017.02.039

Register to see more suggestions

Mendeley helps you to discover research relevant for your work.

Already have an account?

Save time finding and organizing research with Mendeley

Sign up for free