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Diferrocenyl tosyl hydrazone with an ultrastrong NH⋯Fe hydrogen bond as double click switch

Chemical Communications (2015) 51(8) 1514-1516
DOI: 10.1039/c4cc08868a
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Abstract

The ultrastrong and short intramolecular NH⋯Fe hydrogen bond in diferrocenyl hydrazone 2 raises the barrier for intramolecular electron transfer in its mixed-valent cation 2+ and is only disrupted by double oxidation to 22+.

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Förster, C., Veit, P., Ksenofontov, V., & Heinze, K. (2015). Diferrocenyl tosyl hydrazone with an ultrastrong NH⋯Fe hydrogen bond as double click switch. Chemical Communications, 51(8), 1514–1516. https://doi.org/10.1039/c4cc08868a

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