New stannyl enamides

Abstract

New stannyl enamines derived from N-ethynyl oxazolidin-2-ones have been obtained. We describe for the first time the preparation of N-ethynyl oxazolidin-2-ones using trimethylsilylethynyl iodonium triflate. The first results of transmetallation and quenching experiments with prochiral carbonyl derivatives to give β-amino alcohols are also described.