Conversion of a myo-inositol derivative into a scyllo-inositol-derived scaffold with C3ν symmetry bearing three axial pyridyl appendages is presented. This pre-organized hexadentate ligand allows complexation of silver(I). The crystal structure of the complex was established. © 2010.
Léo, P. M., Morin, C., & Philouze, C. (2010). Design and synthesis of a cyclitol-derived scaffold with axial pyridyl appendages and its encapsulation of the silver(I) cation. Beilstein Journal of Organic Chemistry, 6, 1022–1024. https://doi.org/10.3762/bjoc.6.115