Abstract
The nucleophilic displacement of iodobenzene with potassium cyanide was carried out in HMPA in the presence of palladium(II) acetate. The reaction obeys the following kinetics;d[C_6H_5CN]/dt=k[Pd(OAc)_2]_0(M_KCN)^2/3A reaction scheme composed of two cycles has been proposed: in one cycle Pd0 activates iodobenzene and in the other cycle Pd2+ assists the dissolution of potassium cyanide.
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CITATION STYLE
Takagi, K., Okamoto, T., Sakakibara, Y., Ohno, A., Oka, S., & Hayama, N. (1976). Nucleophilic Displacement Catalyzed by Transition Metal. III. Kinetic Investigation of the Cyanation of Iodobenzene Catalyzed by Palladium(II). Bulletin of the Chemical Society of Japan, 49(11), 3177–3180. https://doi.org/10.1246/bcsj.49.3177
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