Time-resolved XUV-induced isomerization and H3 formation in C2H4 cation

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Abstract

Using a split-mirror setup attached to a Reaction Microscope at the Free electron LASer in Hamburg (FLASH) we traced as function of time the migration of a hydrogen atom in C2H4+ from one end of the molecule to the other by coincident CH+ + CH3+ fragment detection. In addition, the observed H3++C 2H+ channel provides for the first time evidence for an isomerization-induced formation mechanism of H3+ molecules. © Published under licence by IOP Publishing Ltd.

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Jiang, Y. H., Rudenko, A., Kübel, M., Herrwerth, O., Foucar, L., Kurka, M., … Ullrich, J. (2012). Time-resolved XUV-induced isomerization and H3 formation in C2H4 cation. In Journal of Physics: Conference Series (Vol. 388). Institute of Physics Publishing. https://doi.org/10.1088/1742-6596/388/3/032014

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