Chlorination of toluene to o-chlorotoluene catalyzed by ionic liquids

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Abstract

Ionic liquids with [BMIM], [Et3 NH], and [BPy] cations and Aln Cl−3n+1, Znn Cl−2n+1, and Cun Cl−n+1 anions were used as the catalysts for the chlorination of toluene with Cl2 . The Znn Cl−2n+1 containing ionic liquids with high Lewis acid strength had high catalytic activity for the selective chlorination of toluene to o-chlorotoluene via the electrophilic substitution reaction. Dichlorotoluenes were favorably formed when the Aln Cl−3n+1 containing ionic liquids with both Lewis and Brönsted acid sites were used as the catalysts. When the Cun Cl−n+1 containing ionic liquids with weak Lewis acid strength were used as the catalysts, more benzyl chloride was formed via the radical chlorination of methyl group. When the [BMIM]Cl-2ZnCl2 ionic liquid was used as the catalyst, after reacting at 80◦ C for 8 h, the conversion of toluene was 99.7% and the selectivities of o-chlorotoluene, p-chlorotoluene, m-chlorotoluene, benzyl chloride, and dichlorotoluenes were 65.4%, 26.0%, 4.0%, 0.4%, and 4.2%, respectively. The [BMIM]Cl-2ZnCl2 ionic liquid catalyst had good recycling performance.

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Wang, A., Zhu, X., Yin, H., Fu, Y., & Hou, X. (2018). Chlorination of toluene to o-chlorotoluene catalyzed by ionic liquids. Catalysts, 8(11). https://doi.org/10.3390/catal8110532

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