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Paramagnetic platinum-rhodium octamers bridged by halogen ions to afford a quasi-1D system

Angewandte Chemie - International Edition (2005) 44(34) 5459-5464
DOI: 10.1002/anie.200501049
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Abstract

(Chemical Equation Presented) Down to the wire: A new class of 1D chain, [-Pt-Rh-Pt4-Rh-Pt-Cl-]n, composed of Pt-Pt and Pt-Rh dimeric complexes linked through metal-metal bonds has been prepared (see structure). This chain of mixed-valent metals (PtII/PtIII and RhII/RhIII) contains one unpaired electron in each octameric segment, leading to unique electrical and magnetic properties. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

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Uemura, K., Fukui, K., Nishikawa, H., Arai, S., Matsumoto, K., & Oshio, H. (2005). Paramagnetic platinum-rhodium octamers bridged by halogen ions to afford a quasi-1D system. Angewandte Chemie - International Edition, 44(34), 5459–5464. https://doi.org/10.1002/anie.200501049

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