Synthesis and Characterization of Graft Copolymer of Dextran and 2-Acrylamido-2-methylpropane Sulphonic Acid

Abstract

A novel biodegradable graft copolymer of dextran (Dx) and 2-acrylamido-2-methyl-1-propane sulphonic acid (AMPS) was synthesized by grafting poly-AMPS chains onto dextran backbone by free radical polymerization using ceric ammonium nitrate (CAN) as an initiator. Different amounts of AMPS were used to synthesize four different grades of graft copolymers with different side chain lengths. These grafted polymers were characterized by elemental analysis, FTIR, 1 HNMR, rheological technique, scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and X-ray diffractometry (XRD). They exhibited efficient flocculation performance in kaolin suspension.