Abstract
The 'dynamic spatial demand' of Frechet-type dendrons is compared with that of 'conventional' building blocks by evaluation of the deslipping behavior of dendritic rotaxanes (see picture). This method leads to a ranking list of the size of voluminous building blocks, which will be useful for the rating of steric effects and the design and synthesis of new rotaxanes or less-stable pseudo-rotaxanes.
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Hübner, G. M., Nachtsheim, G., Li, Q. Y., Seel, C., & Vögtle, F. (2000). The spatial demand of dendrimers: Deslipping of rotaxanes. Angewandte Chemie - International Edition, 39(7), 1269–1272. https://doi.org/10.1002/(SICI)1521-3773(20000403)39:7<1269::AID-ANIE1269>3.0.CO;2-W
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