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Directed meta-metalation using alkali-metal-mediated zincation

Angewandte Chemie - International Edition (2006) 45(23) 3775-3778
DOI: 10.1002/anie.200600720
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Abstract

(Figure Presented) Move over directed ortho-metalation, here comes directed meto-metalation. The unprecedented meto-zincation of two anilides by a synergic mixed sodium/zinc dialkyl-amide base is presented. The orientation of the deprotonation of the anilides is remarkably switched to the meta site using this heterometallic mixed-metal system. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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Armstrong, D. R., Clegg, W., Dale, S. H., Hevia, E., Hogg, L. M., Honeyman, G. W., & Mulvey, R. E. (2006). Directed meta-metalation using alkali-metal-mediated zincation. Angewandte Chemie - International Edition, 45(23), 3775–3778. https://doi.org/10.1002/anie.200600720

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