Electronic Communication as a Transferable Property of Molecular Bridges?

Abstract

Electronic communication through molecular bridges is important for different types of experiments, such as single-molecule conductance, electron transfer, superexchange spin coupling, and intramolecular singlet fission. In many instances, the chemical structure of the bridge determines how the two parts it is connecting communicate, and does so in ways that are transferable between these different manifestations (for example, high conductance often correlates with strong antiferromagnetic spin coupling, and low conductance due to destructive quantum interference correlates with ferromagnetic coupling). Defining electronic communication as a transferable property of the bridge can help transfer knowledge between these different areas of research. Examples and limits of such transferability are discussed here, along with some possible directions for future research, such as employing spin-coupled and mixed-valence systems as structurally well-controlled proxies for understanding molecular conductance and for validating first-principles theoretical methodologies, building conceptual understanding for the growing experimental work on intramolecular singlet fission, and developing measures for the transferability of electronic communication as a bridge property.