Characterization of biopolymeric films based on cassava starch, chitosan and carnauba wax

Abstract

Biopolymer films can advantageously substitute polymers of petrochemical origin in several areas, such as packaging of fruits and vegetables. As these products exhibit breathability and perspiration even after harvesting, barrier properties and water resistance of the packaging material are crucial. In this work, biopolymer films based on cassava starch (0-3%), chitosan (0-3%), carnauba wax (0; 0.2%) and glycerol (0,6%) were obtained and their properties of interest were determined. The wax incorporation reduced on average 20% of the water vapor transmission rate, WVTR, in relation to the films without wax. Among the films containing wax, 1c (3% starch) and 2c (2% starch; 1% chitosan) presented lower values of WVTR, 12.55 g / m²h and 12.42 g / m²h respectively, were then subjected to other characterizations that revealed that the partial replacement of starch by chitosan did not affect the film thickness, caused a decrease of 14% in its solubility and improved mechanical properties, which means increase in its potential for the intended application.