Study of Addition Metal (Ti, Zn) Dopan on the Structure of NASICON as Solid Electrolyte Batteries

Abstract

This study aims to analysized the effect of addition doped metal (Ti and Zn) on NASICON structure to morphology, materials structure, and electrochemical performance especially ionic conductivity properties. NASICON is a sodium super ionic conductor that it could be as solid electrolyte batteries. One of the problems that exist in the secondary battery is the low working temperature of the electrolyte, which makes it easy to explode when exposed to free air. The common electrolyte in liquid phase, so NASICON as replacement alternative. The synthesis method used is the solid-state reaction method by mixing sodium carbonate, silicon dioxide, zirconium oxide, ammonium dihydrogen phosphate, doped metal (titanium oxide and zinc oxide) and some anhydrous ethanol into a planetary ball mill, dried then calcined. Then the material is pressed to produce pellets and the sintered. The doping used varies from 0 to 5 mol% of titanium and zinc. XRD results showed that all variations in titanium doped had found rhombohedral and monoclinic. whereas in zinc doping also have those phase. The highest ionic conductivity is 7.8x10 -3 S/m on 2% mol Zinc Addition