Abstract
The MOF-type Ni2(dobpdc) shows a high chemical stability towards SO2, high capacity for SO2 capture at low pressure (4.3 mmol g−1 at 298 K and up to 0.05 bar), and exceptional cycling performance. Fluorescence experiments demonstrated the SO2 detection properties of Ni2(dobpdc) with a remarkable SO2 detection selectivity. Finally, time-resolved photoluminescence experiments provided a plausible mechanism of SO2 detection by this Ni(ii)-based MOF material.
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CITATION STYLE
López-Cervantes, V. B., Kim, D. W., Obeso, J. L., Martínez-Ahumada, E., Amador-Sánchez, Y. A., Sánchez-González, E., … Solis-Ibarra, D. (2023). Detection of SO2 using a chemically stable Ni(ii)-MOF. Nanoscale, 15(30), 12471–12475. https://doi.org/10.1039/d3nr02936k
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