A one pot method for preparing an antibacterial superabsorbent hydrogel with a Semi-IPN structure based on tara gum and polyquaternium-7

Abstract

An antibacterial superabsorbent polymer was prepared by graft polymerization of acrylic acid onto tara gum polysaccharide, by adding N,N-dimethyl-N-2-propenyl-2-propen-1-aminium chloride and a polymer with 2-propenamide (polyquaternium-7, PQ7) as an antibacterial agent. The effects of the amount of PQ7 in the hydrogel on its swelling ratio were investigated and maximum swelling ratios of 712 g/g and 68 g/g, in distilled water and 0.9 wt % NaCl solution were attained with 0.5 g PQ7 per gram of tara gum. The superabsorbent hydrogel was characterized by using Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy and thermal gravimetric analysis. The results showed that poly (acrylic acid) was successfully grafted onto tara gum and a three-dimensional network structure formed with PQ7 chains penetrated in the networks. The antibacterial properties of these superabsorbent hydrogels against Staphylococcus aureus and Escherichia coli improved with increasing PQ7 content. This study demonstrates a method of preparing novel functional superabsorbent hydrogels.