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Planar three-coordinate iron(ii) complexes supported by sterically demanding -Si(SiMe3)2(SiMe2tBu) ligands

Dalton Transactions (2024) 53(4) 1421-1424
DOI: 10.1039/d3dt04130a
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Abstract

Sterically demanding organosilyl ligands support the formation of coordinatively unsaturated complexes. In this study, we found that using the ligand -Si(SiMe3)2(SiMe2tBu) affords exclusively planar three-coordinate iron bis(silyl) complexes that show good catalytic performance in the hydrosilylation of acetophenone.

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Ishii, R., & Sunada, Y. (2024). Planar three-coordinate iron(ii) complexes supported by sterically demanding -Si(SiMe3)2(SiMe2tBu) ligands. Dalton Transactions, 53(4), 1421–1424. https://doi.org/10.1039/d3dt04130a

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