Platinum corroles

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Abstract

Platinum has been inserted into corroles for the first time and three oxidized PtIV(corrole.2−)ArAr′ complexes have been structurally characterized. The Soret maxima of these complexes exhibit an unusually strong dependence on the meso-aryl substituents on the corrole, indicating aryl → corrole.2− charge transfer character in these transitions. © 2014 The Partner Organisations.

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Alemayehu, A. B., Vazquez-Lima, H., Beavers, C. M., Gagnon, K. J., Bendix, J., & Ghosh, A. (2014). Platinum corroles. Chemical Communications, 50(76), 11093–11096. https://doi.org/10.1039/c4cc02548b

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